Catalytic formation of an amide hydroperoxide and hydrogen peroxide using rhodium complexes and dioxygen/dihydrogen mixtures
Abstract
A rhodium(III) complex in N,N-dimethylacetamide solution under a 1 atm O2/H2 mixture catalyses concomitant formation of the hydroperoxide MeC(O)N(Me)CH2OOH and hydrogen peroxide.