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Issue 18, 1989
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An η2 transition state for the insertion of [Pd(dppe)] fragments into the phosphorus–carbon bonds of phosphiranepentacarbonyltungsten complexes. Crystal and molecular structures of (2R,3S,4R)- and (2R,3S,4S)-[Pd(dppe)(CHPhCHPhPPh)-W(CO)5], dppe = 1,2-bis(diphenylphosphanyl)ethane

Abstract

Evidence for a transition state involving η2 co-ordination of a P–C bond to [Pd(dppe)] is obtained from an analysis of the insertion of [Pd(dppe)] fragments into (E)- and (Z)-[W(CO)5(PPh–CHPh–CHPh)] complexes.

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Article type: Paper
DOI: 10.1039/C39890001389
J. Chem. Soc., Chem. Commun., 1989, 1389-1390

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    An η2 transition state for the insertion of [Pd(dppe)] fragments into the phosphorus–carbon bonds of phosphiranepentacarbonyltungsten complexes. Crystal and molecular structures of (2R,3S,4R)- and (2R,3S,4S)-[Pd(dppe)(CHPhCHPhPPh)-W(CO)5], dppe = 1,2-bis(diphenylphosphanyl)ethane

    D. Carmichael, P. B. Hitchcock, J. F. Nixon, F. Mathey and L. Ricard, J. Chem. Soc., Chem. Commun., 1989, 1389
    DOI: 10.1039/C39890001389

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