A series of metal–metal bonded dimeric ruthenium porphyrin complexes have been characterized by means of X-ray absorption spectroscopy, Ru–Ru bond lengths for Ru2.5+ and Ru3+ complexes having been determined by EXAFS to be 2.29 and 2.22 Å, respectively; electronic configurations also have been confirmed by X-ray absorption near edge spectroscopy.
H. Asahina, M. B. Zisk, B. Hedman, J. T. McDevitt, J. P. Collman and K. O. Hodgson, J. Chem. Soc., Chem. Commun., 1989, 1360 DOI: 10.1039/C39890001360
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