The structure and absolute configuration of solanapyrone D (2) offers further indirect evidence that solanapyrone A (1) and D (2) are biosynthesized via intramolecular Diels–Alder reactions.
H. Oikawa, T. Yokota, A. Ichihara and S. Sakamura, J. Chem. Soc., Chem. Commun., 1989, 1284 DOI: 10.1039/C39890001284
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