The building blocks and the origin of hydrogen and oxygen atoms in solanapyrone A (1) were determined by incorporation experiments employing sodium [1-13C]-, [1,2-13C2]-, [1-13C, 18O2]-, [1-13C, 2H3]-, [2-13C, 2H3]acetates and [S-13CH3] methionine; the labelling pattern supports the hypothesis that (1) is biosynthesized via the intramolecular Diels–Alder reaction.
H. Oikawa, T. Yokota, T. Abe, A. Ichihara, S. Sakamura, Y. Yoshizawa and J. C. Vederas, J. Chem. Soc., Chem. Commun., 1989, 1282 DOI: 10.1039/C39890001282
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