Enediamide complexes of hafnium; X-ray structure of [(C5Me5)Hf(PriNCHCHNPri)(µ-H)]2
Abstract
The new hafnium complex (η5-C5Me5)Hf(Pri-DAB)Cl (Pri-DAB =N,N′-di-isopropyl-1,4-diazabuta-1,3-diene), containing an enediamide ancillary ligand, a precursor to methyl, propynyl, acyl and hydride derivatives is reported; the structure of [(η5-C5Me5)Hf(Pri-DAB)(µ-H)]2 has been determined by X-ray diffraction.