Azido(tetraphenylporphyrinato) complexes of CrIII, MnIII, and FeIII catalyse selective, low temperature hydroxylation of isobutane with molecular oxygen and provide many turnovers in the absence of added co-reductants.
P. E. Ellis and J. E. Lyons, J. Chem. Soc., Chem. Commun., 1989, 1187 DOI: 10.1039/C39890001187
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