1,2-Epoxycycloalkanes from C5 to C8 and cis-stilbene oxide are respectively hydrolysed to the corresponding (–)-(R,R)-trans-diols and to (+)-(R,R)-1,2-diphenylethane-1,2-diol by both the microsomal and the cytosolic epoxide hydrolase of rabbit liver, the former enzyme being more active and giving higher enantiomeric excesses.
G. Bellucci, I. Capitani, C. Chiappe and F. Marioni, J. Chem. Soc., Chem. Commun., 1989, 1170 DOI: 10.1039/C39890001170
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