Electrochemical carbon-skeleton rearrangements catalysed by hydrophobic vitamin B12 immobilised in a polymer-coated electrode
Abstract
A glassy carbon electrode was coated with a polymer species derived from a hydrophobic vitamin B12 and Araldite CT-200,and the immobilised cobalt complex catalysed the electrochemical carbon-skeleton rearrangements of alkyl halides having electron-withdrawing groups.