Trimethylphosphine-co-ordinated π-allylpalladium complexes [(π-allyl)Pd(PMe3)2]X(X = halide) undergo CO insertion into the palladium–allyl bond to give 3-butenoylpalladium complexes under mild conditions.
F. Ozawa, T. Son, K. Osakada and A. Yamamoto, J. Chem. Soc., Chem. Commun., 1989, 1067 DOI: 10.1039/C39890001067
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