The dimeric precursor complex {Rh2[µ-S(CH2)3N(Me)2]2(Cod)2}, (cod = cyclo-octa-1,5-diene), with PPh3 catalyses the hydroformylation of hex-1-ene, under mild conditions, into heptanals with high yields and selectivities; owing to the presence of the amine group the rhodium catalyst can be quantitatively recovered from the reaction mixture by adding dilute H2SO4, and reused without loss of activity.
J. C. Bayón, J. Real, C. Claver, A. Polo and A. Ruiz, J. Chem. Soc., Chem. Commun., 1989, 1056 DOI: 10.1039/C39890001056
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