The poly-N-acylated derivatives (1b), (1c), (1d), and (2d) of the macrocyclic polyamines [18]-N6(1a) and [30]-N10(2a) form Langmuir monolayers in which the macrocycle lies flat on the water surface while the alkane chains tilt upright in the compressed film.
J. Malthête, D. Poupinet, R. Vilanove and J. Lehn, J. Chem. Soc., Chem. Commun., 1989, 1016 DOI: 10.1039/C39890001016
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