Geometrical parameters and vibrational frequency data for the dimer of monochlorogallane obtained by ab initio calculations show excellent agreement with experimental values; the dissociation energy of Ga2Cl2H4 to the GaClH2 monomers and GaCl + H2 has been calculated.
K. Lammertsma and J. Leszczyński, J. Chem. Soc., Chem. Commun., 1989, 1005 DOI: 10.1039/C39890001005
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