α-Dichlorophosphine (3), easily obtained by chemoselective phosphonate reduction, is a precursor of the unhindered C-chlorophosphaethylene (4) and a synthetic equivalent of the phospha-acetylene (5).
J. C. Guillemin, M. Le Guennec and J. M. Denis, J. Chem. Soc., Chem. Commun., 1989, 988 DOI: 10.1039/C39890000988
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