Mn-porphyrins catalyse the epoxidation of various alkenes by magnesium monoperoxyphthalate: with 0.125–1% of tetra-2,6-dichlorophenylporphinatomaganese(III) acetate as a catalyst, alkene conversion is nearly complete within 0.5–5 minutes at 0 °C and good epoxide yields (60–93%) are obtained.
C. Querci and M. Ricci, J. Chem. Soc., Chem. Commun., 1989, 889 DOI: 10.1039/C39890000889
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