Hydroxyquinone annelation
Abstract
The epoxidation reaction of alkoxyallene (4a) produced epoxy ketoaldehyde (5a) through an intermediate oxyallyl zwitterion; an intramolecular aldol reaction, followed by air oxidation produced hydroxyquinone (6).
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J. Chem. Soc., Chem. Commun., 1989, 867-869
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Hydroxyquinone annelation
M. A. Tius, J. M. Cullingham and S. Ali, J. Chem. Soc., Chem. Commun., 1989, 867 DOI: 10.1039/C39890000867
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