A low temperature spectroscopic study of the facile arene exchange by phosphines and phosphites in the air-sensitive 19 electron complexes [FeICp(η6-arene)], (Cp = cyclopentadienyl, η5-C5H5), shows an associative pathway in the rate limiting step, which suggests a fast pre-equilibrium generating a 17 electron species.
J. Ruiz and D. Astruc, J. Chem. Soc., Chem. Commun., 1989, 815 DOI: 10.1039/C39890000815
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