Issue 12, 1989

Synergistic effect of lipophilic carboxylic acids and heterocyclic axial ligands in alkene epoxidation by hydrogen peroxide catalysed by manganese(III) tetra-aryl porphyrins

Abstract

The rate of alkene epoxidation promoted by 30% H2O2 and catalysed by MnIII tetra (2,6-dichlorophenyl)porphyrin is strongly enhanced by the addition of lipophilic carboxylic acids and lipophilic imidazole or pyridine axial ligands, in 1–8 : 1 and 1 : 1 molar ratios with respect to the porphyrin.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 779-780

Synergistic effect of lipophilic carboxylic acids and heterocyclic axial ligands in alkene epoxidation by hydrogen peroxide catalysed by manganese(III) tetra-aryl porphyrins

P. L. Anelli, S. Banfi, F. Montanari and S. Quici, J. Chem. Soc., Chem. Commun., 1989, 779 DOI: 10.1039/C39890000779

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