A highly stereocontrolled construction of 1,2-trans-β-glycosidic linkage with or without neighbouring-group participation has been achieved using benzyl- or benzoyl-protected glycopyranosyl phosphates as glycosyl donors in the presence of trimethylsilyl triflate (TMSOTf).
S. Hashimoto, T. Honda and S. Ikegami, J. Chem. Soc., Chem. Commun., 1989, 685 DOI: 10.1039/C39890000685
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