Trichodiene was rigorously proven to be a biosynthetic precursor to the major trichothecenes in Fusarium culmorum: 3-acetyldeoxynivalenol and sambucinol; bazzanene, an unnatural diastereoisomer of trichodiene (with a β-methyl at C-15), was not incorporated into trichothecenes.
L. O. Zamir, M. J. Gauthier, K. A. Devor, Y. Nadeau and F. Sauriol, J. Chem. Soc., Chem. Commun., 1989, 598 DOI: 10.1039/C39890000598
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