An efficient and stereospecific synthesis of 2′-deoxycadeguomycin (3) from the novel 7-deazapurine derivatives 2-amino-4-chloropyrrolo[2,3-d]pyrimidine-5-carbonitrile (10) or methyl 2-amino-4-chloropyrrolo[2,3-d]pyrimidine-5-carboxylate (12) has been accomplished.
K. Ramasamy, R. K. Robins and G. R. Revankar, J. Chem. Soc., Chem. Commun., 1989, 560 DOI: 10.1039/C39890000560
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