The ruthenium cluster [Ph4P][Ru3(CO)10(PhNCHO)] has been structurally characterised and shown to play an important role, along with its precursor [Ph4P][HRu3(CO)9(PhNCO)], in the hydroxide- or methoxide-promoted reductive carbonylation of nitrobenzene.
S. Bhaduri, H. Khwaja, K. Sharma and P. G. Jones, J. Chem. Soc., Chem. Commun., 1989, 515 DOI: 10.1039/C39890000515
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