Selective hydroxylation (or ketonization) of cyclic alkanes and conversion of ethers to esters and of secondary alcohols to ketones, with significant rates (up to ca. 1 turnover per minute at room temperature), were achieved by using hypochlorite as oxidant and a choice of ruthenium(II) complexes as catalysts, in a biphastic water–dichloromethane system.
M. Bressan and A. Morvillo, J. Chem. Soc., Chem. Commun., 1989, 421 DOI: 10.1039/C39890000421
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