The reaction of β-cyclodextrin complexes of substituted thioacetates (1) with sodium hypochlorite in aqueous medium gives optically active α,α-dichlorosulphoxides (2) in good yields with an enantiomeric excess (e.e) of up to 53%.
K. R. Rao and P. B. Sattur, J. Chem. Soc., Chem. Commun., 1989, 342 DOI: 10.1039/C39890000342
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