RuO2·xH2O needs to be reduced quite substantially before it can function as a hydrogen catalyst; without reduction, RuO2·xH2O is a strong oxidant, capable of oxidising MV+˙, I–, Br–, Cl–, Ru(bpy)32+, and Fe(phen)32+(bpy = 2,2′-bipyridine and phen = 1,10-phenanthroline).
A. Mills and G. Williams, J. Chem. Soc., Chem. Commun., 1989, 321 DOI: 10.1039/C39890000321
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