Total synthesis of an antibiotic Andrimid was accomplished stereospecifically; it was shown that the chiralities at C-3 and C-4 should be R and S, respectively, and the presence of the (4S)-methyl group is important for the activity.
W. McWhorter, A. Fredenhagen, K. Nakanishi and H. Komura, J. Chem. Soc., Chem. Commun., 1989, 299 DOI: 10.1039/C39890000299
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