A new use of trialkyl-(1-methylindol-2-yl)borates for the synthesis of 2-substituted indoles involving the palladium catalysed cross-coupling with vinylic and aromatic halides, or a facile alkyl migration from boron to carbon without an additional electrophile is described.
M. Ishikura and M. Terashima, J. Chem. Soc., Chem. Commun., 1989, 135 DOI: 10.1039/C39890000135
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