Issue 2, 1989

Novel backbone rearrangement of steroids: formation of (20R and 20S) 1β,14β-dimethyl-18,19-dinor-5β,8α,9β,10α-cholest-13(17)-enes

Abstract

Two new 1-methyl rearranged sterenes were formed from cholestan-3β-ol and related compounds by a novel backbone reaction, catalysed by K10-montmorillonite; their structures were determined by 1H and 13C n.m.r. spectroscopy.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 133-135

Novel backbone rearrangement of steroids: formation of (20R and 20S) 1β,14β-dimethyl-18,19-dinor-5β,8α,9β,10α-cholest-13(17)-enes

O. Sieskind, J. Kintzinger and P. Albrecht, J. Chem. Soc., Chem. Commun., 1989, 133 DOI: 10.1039/C39890000133

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