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Issue 1, 1989
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Conversion of α,β-unsaturated ketone complexes into α,β-unsaturated ketene complexes

Abstract

Treatment of (α,β-unsaturated ketone)tricarbonyliron(0) complexes with organolithium reagents under an atmosphere of carbon monoxide gave products which were identified as (α,β-unsaturated ketene)tricarbonyliron(0) complexes based on a crystal structure analysis of [PhCH[double bond, length half m-dash]CHC(Me)[double bond, length half m-dash]C–O](CO)3Fe(0)(2), the product obtained form (PhCH[double bond, length half m-dash]CHC[double bond, length half m-dash]OMe)(CO)3Fe(0)(1).

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Article type: Paper
DOI: 10.1039/C39890000021
J. Chem. Soc., Chem. Commun., 1989, 21-22

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    Conversion of α,β-unsaturated ketone complexes into α,β-unsaturated ketene complexes

    N. W. Alcock, T. N. Danks, C. J. Richards and S. E. Thomas, J. Chem. Soc., Chem. Commun., 1989, 21
    DOI: 10.1039/C39890000021

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