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Issue 8, 1989

Epoxidation catalysed by MnIIITPPCl using dioxygen activated by a system containing N-hydroxyphthalimide and styrene, 2-norbornene or indene

Abstract

The catalytic epoxidation of alkenes by molecular oxygen activated in the system containing N-hydroxyphthalimide (NHPI) and active alkenes such as styrene, 2-norbornene or indene is reported. The transient intermediates, alkyl hydroperoxides formed by autoxidation of NHPI and the active alkenes are proposed as oxygen sources which transfer mono-oxygen to MnIIITPPCl.

Article information


J. Chem. Soc., Perkin Trans. 2, 1989, 951-956
Article type
Paper

Epoxidation catalysed by MnIIITPPCl using dioxygen activated by a system containing N-hydroxyphthalimide and styrene, 2-norbornene or indene

S. Ozaki, T. Hamaguchi, K. Tsuchida, Y. Kimata and M. Masui, J. Chem. Soc., Perkin Trans. 2, 1989, 951 DOI: 10.1039/P29890000951

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