Ab initio quantum mechanical studies of the Ag + SiO complex using double zeta (DZ) and double zeta plus polarization (DZP) function basis sets, including configuration interaction, show that the silver atom is O-bonded in a quasi-linear orientation, not Si-bonded and bent as previously concluded from experimental studies.
G. E. Quelch, R. S. Grev and H. F. Schaefer, J. Chem. Soc., Chem. Commun., 1989, 1498 DOI: 10.1039/C39890001498
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