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Issue 21, 1989
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C–H activation in a co-ordinated catenand: ortho-metallation of cat30 by palladium(II)

Abstract

Insertion of Pd2+ into the catenand ligand cat30 yields the monocation [PdII(cat30–H)]+via ortho-metallation of one of the ligand phenyl rings to give square planar co-ordination by an N3C donor set, Pd–N(1)= 2.139(11), Pd–N(3)= 2.286(10), Pd–N(4)= 1.961(10), Pd–C(71)= 2.017(7)Å; the N-atom N(2) associated with the phenanthroline (phen) chelate incorporating N(1) lies 2.559(11)Å from the metal centre making this phen moiety monodenatate to the PdII centre.

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Article information


J. Chem. Soc., Chem. Commun., 1989, 1663-1665
Article type
Paper

C–H activation in a co-ordinated catenand: ortho-metallation of cat30 by palladium(II)

A. J. Blake, C. O. Dietrich-Buchecker, T. I. Hyde, J. Sauvage and M. Schröder, J. Chem. Soc., Chem. Commun., 1989, 1663
DOI: 10.1039/C39890001663

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