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Issue 21, 1989
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Photochemical chlorodecarboxylation via an electron transfer mechanism

Abstract

A new method of chlorodecarboxylation of carboxylic acids via N-acyloxyphthalimides is developed; the reaction proceeds upon irradiation of N-acyloxyphthalimides in the presence of 1,4-diazabicyclo[2.2.2]octane in ButOH–CCl4–H2O (53:42:5 v/v) in moderate to high yields.

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Article information


J. Chem. Soc., Chem. Commun., 1989, 1636-1637
Article type
Paper

Photochemical chlorodecarboxylation via an electron transfer mechanism

K. Okada, K. Okamoto and M. Oda, J. Chem. Soc., Chem. Commun., 1989, 1636
DOI: 10.1039/C39890001636

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