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Issue 17, 1989
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Generation of alkoxyl radicals from O-alkyl benzenesulphenates

Abstract

Representative examples (1,2, and 3) of primary, secondary, and tertiary alkyl benzenesulphenates, when treated with tributylstannane, generate alkoxy radicals which undergo characteristic β-scission or intramolecular addition reactions; the rate constants of these processes have been determined.

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Article information


J. Chem. Soc., Chem. Commun., 1989, 1202-1203
Article type
Paper

Generation of alkoxyl radicals from O-alkyl benzenesulphenates

A. L. J. Beckwith, B. P. Hay and G. M. Williams, J. Chem. Soc., Chem. Commun., 1989, 1202
DOI: 10.1039/C39890001202

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