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Issue 13, 1989
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Spectroscopic properties and redox chemistry of the phosphorescent excited state of [Au2(dppm)2]2+[dppm = bis(diphenylphosphino)methane]

Abstract

The complex [Au2(dppm)2]2+[dppm = bis(diphenylphosphino)methane] exhibits a long-lived room temperature photoluminescence in fluid solutions (emission maximum, 565 nm; τ0, 17.0 µs; ϕem, 0.15); the phosphorescent excited state of [Au2(dppm)2]2+ undergoes oxidative and reductive quenching with methyl viologen and N,N,N′,N′-tetramethyl-p-phenylenediamine, respectively, and can be quenched by organic halides.

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Article information


J. Chem. Soc., Chem. Commun., 1989, 885-886
Article type
Paper

Spectroscopic properties and redox chemistry of the phosphorescent excited state of [Au2(dppm)2]2+[dppm = bis(diphenylphosphino)methane]

C. Che, H. Kwong, V. W. Yam and K. Cho, J. Chem. Soc., Chem. Commun., 1989, 885
DOI: 10.1039/C39890000885

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