Issue 11, 1988
From the journal:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

Kinetics of β-hydroxyl elimination from [(H2O)mCuIICH2C(CH3)2Oh]+ in aqueous solution. A pulse-radiolysis Study

Haim Cohen  and  Dan Meyerstein  

Abstract

The reaction of ˙CH2C(CH3)2OH with Cuaq+ yields the short-lived transient complex [CuIICH2C(CH3)2OH]aq+. The spectrum of the latter complex is reported. [CuIICH2C(CH3)2OH]aq+ decomposes into Cuaq++ CH2[double bond, length as m-dash]C(CH3)2+OH–. The specific rate of this reaction is 5.0 × 104+ 8.6 × 107[H3O+] S–1. The kinetics are discussed in comparison with those of analogous reactions reported earlier.

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Article information

DOI
https://doi.org/10.1039/F19888404157
Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1988,84, 4157-4160

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Kinetics of β-hydroxyl elimination from [(H2O)mCuIICH2C(CH3)2Oh]+ in aqueous solution. A pulse-radiolysis Study

H. Cohen and D. Meyerstein, J. Chem. Soc., Faraday Trans. 1, 1988, 84, 4157 DOI: 10.1039/F19888404157

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