Solid-state structures of platinum–sulphur–nitrogen stacking compounds: [Pt(S2N2)(PMe2Ph)2], [Pt(S2N2H)(PMe2Ph)2]Cl, [Pt(S2N2H)(PMe2Ph)2]PF6, and [Pd(S2N2H)(PMe2Ph)2]BF4
Abstract
The X-ray crystal structures of [Pt(S2N2)(PMe2Ph)2], [Pt(S2N2H)(PMe2Ph)2]Cl, [Pt(S2N2H)(PMe2Ph)2] PF6, and [Pd(S2N2H)(PMe2Ph)2]BF4 are reported. The effect of protonation of the S2N22– ligand and the requirements for stacking are discussed.