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Issue 24, 1988
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First examples of η1-ligated 1,2,4-triphosphacyclopentadienyl ring systems. Synthesis and fluxional behaviour of trans-[MCl(C2R2P3)(PEt3)2], (R = But, adamantyl), (M = Pd, Pt); crystal and molecular structures of trans-[PtX(C2But2P3)(PR3)2], (X = Cl, R = Et; X = I, R = Ph)

Abstract

First examples of η1-ligated 1,2,4-triphosphacyclopentadienyl ring systems are described and structural features and solution fluxional behaviour are discussed.

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Article type: Paper
DOI: 10.1039/C39880001615
J. Chem. Soc., Chem. Commun., 1988, 1615-1617

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    First examples of η1-ligated 1,2,4-triphosphacyclopentadienyl ring systems. Synthesis and fluxional behaviour of trans-[MCl(C2R2P3)(PEt3)2], (R = But, adamantyl), (M = Pd, Pt); crystal and molecular structures of trans-[PtX(C2But2P3)(PR3)2], (X = Cl, R = Et; X = I, R = Ph)

    R. Bartsch, D. Carmichael, P. B. Hitchcock, M. F. Meidine, J. F. Nixon and G. J. D. Sillett, J. Chem. Soc., Chem. Commun., 1988, 1615
    DOI: 10.1039/C39880001615

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