Issue 24, 1988
From the journal:

Journal of the Chemical Society, Chemical Communications

First examples of η1-ligated 1,2,4-triphosphacyclopentadienyl ring systems. Synthesis and fluxional behaviour of trans-[MCl(C2R2P3)(PEt3)2], (R = But, adamantyl), (M = Pd, Pt); crystal and molecular structures of trans-[PtX(C2But2P3)(PR3)2], (X = Cl, R = Et; X = I, R = Ph)

Rainer Bartsch,   Duncan Carmichael,   Peter B. Hitchcock,   Mohamed F. Meidine,   John F. Nixon  and  Gary J. D. Sillett  

Abstract

First examples of η1-ligated 1,2,4-triphosphacyclopentadienyl ring systems are described and structural features and solution fluxional behaviour are discussed.

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Article information

DOI
https://doi.org/10.1039/C39880001615
Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 1615-1617

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First examples of η1-ligated 1,2,4-triphosphacyclopentadienyl ring systems. Synthesis and fluxional behaviour of trans-[MCl(C2R2P3)(PEt3)2], (R = But, adamantyl), (M = Pd, Pt); crystal and molecular structures of trans-[PtX(C2But2P3)(PR3)2], (X = Cl, R = Et; X = I, R = Ph)

R. Bartsch, D. Carmichael, P. B. Hitchcock, M. F. Meidine, J. F. Nixon and G. J. D. Sillett, J. Chem. Soc., Chem. Commun., 1988, 1615 DOI: 10.1039/C39880001615

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