Issue 23, 1988

Generation and interconversions of the di- and tri-nuclear platinum complexes [Pt2H2(dppe)2], [Pt2H3(dppe)2]+, and [Pt3H3(dppe)3]+. Crystal and molecular structure of [Pt3H3(dppe)3]+[BEt4], (dppe = Ph2PCH2CH2PPh2)

Abstract

Multinuclear n.m.r. and crystallographic studies on [Pt2H2(dppe)2], [Pt2H3(dppe)2]+, and [Pt3H3(dppe)3]+ are described, the structure of the latter being unambiguously established for the first time.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 1554-1556

Generation and interconversions of the di- and tri-nuclear platinum complexes [Pt2H2(dppe)2], [Pt2H3(dppe)2]+, and [Pt3H3(dppe)3]+. Crystal and molecular structure of [Pt3H3(dppe)3]+[BEt4], (dppe = Ph2PCH2CH2PPh2)

D. Carmichael, P. B. Hitchcock, J. F. Nixon and A. Pidcock, J. Chem. Soc., Chem. Commun., 1988, 1554 DOI: 10.1039/C39880001554

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