Issue 21, 1988
From the journal:

Journal of the Chemical Society, Chemical Communications

Stereochemical and redox properties of palladium complexes of 1,4,10,13-tetrathia-7,16-diazacyclo-octadecane

Gillian Reid,   Alexander J. Blake,   Timothy I. Hyde  and  Martin Schröder  

Abstract

The square planar S4 donor complex [Pd(L1)]2+(L1= 7,16-dimethyl-1,4,10,13-tetrathia-7,16-diazacyclo-octadecane) shows a reversible PdII/I redox couple at E½–0.74 V vs. Fc/Fc+; in contrast, the complex [Pd(L2)]2+(L2= 1,4,10,13-tetrathia-7,16-diazacyclo-octadecane) shows distorted octahedral N2S2+ S2 co-ordination, and a reversible PdII/III couple at E½+0.57 V vs. Fc/Fc+(ferrocene/ferrocinium).

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Article information

DOI
https://doi.org/10.1039/C39880001397
Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 1397-1399

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Stereochemical and redox properties of palladium complexes of 1,4,10,13-tetrathia-7,16-diazacyclo-octadecane

G. Reid, A. J. Blake, T. I. Hyde and M. Schröder, J. Chem. Soc., Chem. Commun., 1988, 1397 DOI: 10.1039/C39880001397

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