Issue 19, 1988

Substitution on five µ-oxo/µ-sulphido incomplete cuboidal MoIV3 ions [Mo3OxS4–x(H2O)9]4+: kinetic effects resulting from the replacement of core oxo by sulphido ligands

Abstract

A 570-fold spread in rate constants (25 °C), [H+]= 2.0 M, is observed for 1 : 1 NCS substitution (of H2O) at Mo on the title complexes, with replacement of core µ3(O) by µ3(S) decreasing (factor of 10), and further replacement of the three µ2(O) by µ2(S) increasing (factor of 570) the rate of substitution.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 1324-1325

Substitution on five µ-oxo/µ-sulphido incomplete cuboidal MoIV3 ions [Mo3OxS4–x(H2O)9]4+: kinetic effects resulting from the replacement of core oxo by sulphido ligands

B. Ooi, M. Martinez and A. G. Sykes, J. Chem. Soc., Chem. Commun., 1988, 1324 DOI: 10.1039/C39880001324

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements