Iron(II) cage complexes [Fe{(1-X, 8-Y)-sar}]2+(X = Y = H, NH2, or NH3+, or X = Me, Y = H, sar = 3,6,10,13,16,19-hexa-azabicyclo[6.6.6]icosane) show high-spin (5T2g origin)⇌ low-spin (1A1g origin) equilibria in solution, characterised by measurements of magnetism and visible and 1H n.m.r. spectra.
L. L. Martin, K. S. Hagen, A. Hauser, R. L. Martin and A. M. Sargeson, J. Chem. Soc., Chem. Commun., 1988, 1313 DOI: 10.1039/C39880001313
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...