Reaction of O-mesylcyanohydrins of furanos-3-uloses with base afforded furanose-3-spiro-5′-[4′-amino-1′,2′-oxathiole-2′,2′-dioxide] derivatives, which on treatment with MeONa/MeOH gave C-[(E)-2-(methoxysulphonyl)-1-(amino)-vinyl] branched-chain sugars, having the same configuration as the starting cyanohydrins.
A. Calvo-Mateo, M. Camarasa, A. Díaz-Ortíz and F. G. de las Heras, J. Chem. Soc., Chem. Commun., 1988, 1114 DOI: 10.1039/C39880001114
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