E.s.r. evidence for the rearrangement at 77 K of ionized allylamine to the distonic radical cation ·CH2CH2CH
NH2
Abstract
The radical cation formed by radiolytic oxidation of prop-2-enylamine (allylamine) in Freon matrices at 77 K is the 3-iminiopropyl distonic species (3-iminium-1-propyl radical) resulting from a 1,2-hydrogen shift in the parent cation.
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NH2