Issue 14, 1988
From the journal:

Journal of the Chemical Society, Chemical Communications

A metal encapsulated boron atom: preparation and structure of [Fe4(CO)12B{AuPPh3}3]

Karen S. Harpp,   Catherine E. Housecroft,   Arnold L. Rheingold  and  Musa S. Shongwe  

Abstract

The preparation and structural characterisation of the heterometallic cluster [Fe4(CO)12B{AuPPh3}3] are described: the new compound is the first example of a structurally characterised cluster containing a naked boron atom, i.e. a discrete metal boride cluster; the boron atom is within bonding contact of all seven metal atoms and this unique environment is reflected by an exceptional downfield n.m.r. shift for the 11B resonance.

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Article information

DOI
https://doi.org/10.1039/C39880000965
Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 965-966

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A metal encapsulated boron atom: preparation and structure of [Fe4(CO)12B{AuPPh3}3]

K. S. Harpp, C. E. Housecroft, A. L. Rheingold and M. S. Shongwe, J. Chem. Soc., Chem. Commun., 1988, 965 DOI: 10.1039/C39880000965

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