Oxidation of secondary C–H bonds of saturated hydrocarbons (C6H12, 2-methylbutane) by H2O2 in the presence of copper or iron perchlorates in pyridine solution yields the ketone and alcohol with alkyl radicals not being intermediates.
Y. V. Geletii, V. V. Lavrushko and G. V. Lubimova, J. Chem. Soc., Chem. Commun., 1988, 936 DOI: 10.1039/C39880000936
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