Mathematical models have been constructed to describe the kinetics of formation of cis-[Pt(NH3)2{d(‥pApGp‥)}] and cis-[Pt(NH3)2{d(‥pGpGp‥)}] from DNA and cisplatin-type systems; the rate constant and entropy of activation of the initial reaction with G indicate that the 5′-phosphate is very important kinetically.
C. Verma, M. Green and R. M. Wing, J. Chem. Soc., Chem. Commun., 1988, 884 DOI: 10.1039/C39880000884
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