Issue 12, 1988

First example of a 1,2,4-triphosphabuta-1,3-diene complex: synthesis and crystal and molecular structure of [Co(η5-C2R2P3)(η4-C2R2HP3)](R = But)

Abstract

Treatment of CoCl2 with Li(C2R2P3)(R = But) in 1,2-dimethoxyethane yields the complex [Co(η5-C2R2P3)(η4-C2R2HP3)] containing a ligated 1,2,4-triphosphacyclopenta-1,3-diene ring system.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 819-820

First example of a 1,2,4-triphosphabuta-1,3-diene complex: synthesis and crystal and molecular structure of [Co(η5-C2R2P3)(η4-C2R2HP3)](R = But)

R. Bartsch, P. B. Hitchcock and J. F. Nixon, J. Chem. Soc., Chem. Commun., 1988, 819 DOI: 10.1039/C39880000819

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