1-Trimethylstannylphospholes as precursors of η5-phospholyl complexes. Synthesis of (η5-phospholyl)trichlorotitanium(IV) complexes
Abstract
Reaction of lithium phospholides with Me3SnCl yields 1-trimethylstannylphospholes, which in toluene–hexane solution react with TiCl4, affording (η5-phospholyl)trichlorotitanium(IV) complexes.